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Molecular gels are formed by the supramolecular assembly of low molecular weight gelators (LMWGs) in organic solvents or water. Despite significant advances in the field, our understanding of how gelator molecules lead to complex self-assembled fibrillar network (SAFIN) is rather poor. Here, we present molecular dynamics simulations to gain insights into the early-stage aggregation of self-assembled fibrillar network (SAFIN) of 12-hydroxyoctadecanamide (12-HSAm) in octane. Our simulations reveal that the hydroxyl group located at the
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