https://www.selleckchem.com/pr....oducts/vacuolin-1.ht
We also showed that NanA-CT catalyzes the regioselective cyclization of a surrogate synthetic substrate, Ant-l-Kyn-N-acetylcysteamine, to give the benzazepine scaffold, while spontaneous cyclization of the dipeptide yielded the alternative kinetically favored benzodiazepine scaffold. The discovery of 1 and the characterization of NanA have expanded the chemical and functional diversities of fungal NRPSs.An enantioselective, radical-based method for the intramolecular hydroamination of alkenes with sulfonamides is reported. These reac
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