https://www.selleckchem.com/pr....oducts/iberdomide.ht
The bulky iodide ligands improve the selectivity for macrocyclization in ring-closing metathesis.The new, formally MII) complexes [Mη3-2-R-allyl)(6,6'-dmbipy)(CO)2Cl] (6,6'-dmbipy = 6,6'-dimethyl-2,2'-bipyridine; 2-R-allyl = allyl for R = H, 2-methallyl for R = CH3) and [Mη3-2-methallyl)(pTol-bian)(CO)2Cl] (pTol-bian = bis(p-tolylimino)acenaphthene) share, in this rare case, the same structural type. The effect of the anionic π-donor ligand X (Cl- vs NCS-) and the 2-R-allyl substituents on the cathodic behavior was explored. Bo
Mi piace
Commento
Condividi
