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In this essay, the second-order rate constants of 25 hydrogen atom transfer (HAT) responses between phenols and PINO and DPPH radicals in acetonitrile at 298 K had been studied. Thermo-kinetic variables ΔG ≠XH) were obtained utilizing a kinetic equation [ΔG ≠ XH/Y = ΔG ≠XH) + ΔG ≠Y)]. Bond dissociation free energies ΔG XH) were determined because of the iBonD HM method, whose details can be obtained at https//pka.luoszgroup.com/bde_prediction. Intrinsic resistance energies ΔG ≠ XH/X and ΔG ≠X) had been de
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