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The structural properties and binding motif of a strongly sigma-electron donating N-heterocyclic carbene are investigated on different transition metal surfaces. The examined cyclic (alkyl)(amino) carbene (CAAC) is found to be mobile on surfaces and molecular islands with short-range order could be found at high coverage. By combining scanning tunneling microscopy (STM), X-ray photoelectron spectroscopy (XPS) and density functional theory (DFT) calculations our study highlights how CAACs bind to the surface, which is of tremendous impor
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