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Birnessite/PMS Fenton-like system degrades phenol via a non-radical method, that involves high valent Mn(V)=O generated through the surface reaction of Mn(III) with adsorbed PMS. While Cu-Bir initiates an extra radical apparatus that involves reactive oxygen species of ⋅O2 - and 1 O2 , additionally the k value of 5Cu-Bir is 1.9 times more than that of Bir. The Fenton-like reaction method associated with Cu-Bir/PMS system is hence proposed as a radical and non-radical cooccurrence system, that involves a synerg
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