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Mechanistic studies expose that the auxiliary team is crucial for C-H activation, and Na2CO3 and an alcoholic solvent perform key roles in assisting the cleavage for the polyfluoroalkylsulfinyl auxiliary.A palladium-catalyzed asymmetric [3+2] cycloaddition reaction of methyleneindolinones with vinylethylene carbonates has been successfully created, which offers a very efficient means for the synthesis of structurally diverse 3,3'-tetrahydrofuryl spirooxindoles in large
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