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The remarkable results of free-standing clusters hold true for surface mounted clusters, in which the interaction with CO is dramatically weakened for those compounds with a PtGe ratio of 11. Our results demonstrate that Ge can be a promising alloying agent to mitigate the deactivation of Pt and that the dopant concentration is a critical factor in the design of advanced catalysts.We investigate a spin-boson inspired model of electron transfer, where the diabatic coupling is given by a position-dependent phase, eiWx. We consider both e
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