https://www.selleckchem.com/pr....oducts/ch7233163.htm
Cyclic voltammograms measured at various scan rates besides temperature and kinetic analyses of RuC2(Re)- produced by steady-state irradiation indicated that the subsequent reaction of RuC2(Re)- proceeds with an observed first-order rate constant of approximately 1.8 s-1 at 298 K and is a unimolecular reaction, independent of the concentrations of both CO2 and RuC2(Re)-.The mechanism of [2 + 2] cycloadditions activated by visible light and catalyzed by bis-cyclometalated Rh(iii) and Ir(iii) photocatalysts was investigated, combining d
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