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For instance, reactions with isocyanides provided heterometallic species by coordination of isocyanides to the nickel center, with no subsequent reduction detected. Isocyanides could also be dissociated at 80 °C. In contrast, hydromagnesiation occurred upon treatment of the heterotrimetallic hydride with carbodiimides, affording C3-symmetric complexes with three heteroleptic magnesium mixed β-diketiminate/amidinate moieties. The hydride-bridged heterotrimetallic complex underwent dehydrogenation reaction with phenyl acetylene to produc
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