https://www.selleckchem.com/pr....oducts/gsk-3008348-h
These results implicate 1,4-dithiins as interesting recognition moieties in the construction of supramolecular receptors.A range of allylic alcohols are shown to readily react with ethereal H2O2 in the presence of catalytic amounts of Na2MoO4-gly or MoO2(acac)2, affording the C═C trans hydroxylation-hydroperoxylation products in good yields with high regio- and stereoselectivity. Use of enantiomers of cyclic substrates resulted in corresponding enantiopure diol-tert-hydroperoxides. The possibility of further conversion
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