https://www.selleckchem.com/pr....oducts/geneticin-g41
The fundamental bandgap Eg of a semiconductor-often determined by means of optical spectroscopy-represents its characteristic fingerprint and changes distinctively with temperature. Here, we demonstrate that in magic sized II-VI clusters containing only 26 atoms, a pronounced weakening of the bonds occurs upon optical excitation, which results in a strong exciton-driven shift of the phonon spectrum. As a consequence, a drastic increase of dEg/dT (up to a factor of 2) with respect to bulk material or nanocrystals of typica
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