https://www.selleckchem.com/pr....oducts/bms-986020.ht
N-Heterocyclic carbenes (NHCs) are commonly prepared by deprotonation of azolium salts using strong anionic bases. This reaction is often unselective, yielding alkali metal NHC complexes or dimerized NHCs. Alternatively, free NHCs are obtained by the dechlorination of 2-chloroazolium salts using electron-rich phosphines. PPh3 , PCy3 , and PtBu3 are unsuitable for Cl+ abstraction, while the sterically encumbered tris(1,3-tert-butylimidazolidin-2-ylidenamino)phosphine 1 selectively removes Cl+ from 2-chloroazolium salts. Since bulky 1
Мне нравится
Комментарий
Перепост
