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Cattle occasionally develop brassica-associated liver disease (BALD) and photosensitisation when grazing turnip or swede (Brassica spp.) forage crops. The liver toxin in these brassica varieties has yet to be discovered. Progoitrin is the dominant glucosinolate in incriminated crops. Apart from goitrin, progoitrin hydrolysis yields the nitrile, 1-cyano-2-hydroxy-3-butene (CH, and the epithionitrile, 1-cyano-2-hydroxy-3,4-epithiobutane (CHE. The two compounds were custom-synthesised. In a small pilot trial, New Zealand White rabbits
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