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This holds for arbitrary arrangements of a large number of molecules, as well as for periodic or aperiodic molecular arrays. © 2020 WILEY-VCH Verlag GmbH Co. KGaA, Weinheim.We resolve the contradiction between two recent experimental studies [Jara-Toro et al., Angew. Chem. Int. Ed. 2017, 56, 2166 and Chao et al. Angew. Chem. Int. Ed. 2019, 131, 1] of the possible catalytic effect of water vapor on CH 3 OH + OH reaction and we extend the rate constant evaluation down to 200 K. The rate constants of the CH 3 OH + OH reaction cata
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