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inding to hERG channels through F656 and Y652 instantaneously. While, the PI3K/Akt/Sp1 axis may play an essential role in the regulation of hERG channels, from the perspective of the long-term effects of Rut (incubating for 24 hours). Importantly, the changes of electrophysiological properties by Rut were the main cause of VA.Cyclometallated complexes are well-known and have found many applications. This article provides a short review on the progress made in the synthesis and application to catalysis of cyclometallated half-sandwich
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