https://www.selleckchem.com/pr....oducts/6-thio-dg.htm
In the past decade, the use of earth-abundant metals in homogeneous catalysis has flourished. In particular, metals such as cobalt and iron have been used extensively in reductive transformations including hydrogenation, hydroboration, and hydrosilylation. Manganese, on the other hand, has been considerably less explored in these reductive transformations. Here, we report a well-defined manganese complex, [Mn( i PrBDI)(OTf)2] (2a; BDI = bipyridinediimine), that is an active precatalyst in the hydroboration of a variety of electronical
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