https://www.selleckchem.com/pr....oducts/cd38-inhibito
In regions close to phase transitions, the off-diagonal elements Γ ij (i ≠ j) are often negative and may attain large magnitudes in relation to the diagonal elements Γ ii . Strong thermodynamic coupling effects cause the transient equilibration trajectories to be strongly curvilinear, causing ingress into the metastable region. If thermodynamic coupling effects are ignored, no such ingress occurs. It is also shown that analogous diffusional forays may lead to emulsion formation in partially miscible liquid mixtures. Copyright ©
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