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The role of substance customization of pristine linen dietary fiber (LF) on its physicochemical and adsorption properties is reported in this contribution. The surface and textural properties for the pristine LF as well as its peroxyacetic acid- (PAF) and chlorite-treated (CF) fibre types were characterized by a few complementary methods spectroscopy (SEM, TEM, FT-IR, and XPS), thermal analysis (DSC and TGA), gas/water adsorption isotherms, and zeta prospective (ξ). The