https://www.selleckchem.com/pr....oducts/tqb-3804-egrf
Biobased farnesene (Far) was polymerized by nitroxide-mediated polymerization in miniemulsions using two different alkoxyamine initiators, the SG1-based and succinimidyl-modified BlocBuilder (NHS-B and Dispolreg 007 (D7). Stable emulsions were observed after 30 h of reaction at 90 °C, where NHS-BB-initiated systems resulted in smaller particles (∼300 nm) than using D7 (∼400 nm). Successful chain extension of the poly(Far) macroinitiators (24,500-39,700 g mol-1) with styrene were achieved using 15 wt % surfactant relative to
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