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Silver nanoparticles were eco-friendly synthesized at room temperature via a Tollens process modified with the stepwise method using eco-friendly precursors (citric acid and acetic acid). The field emission scanning electron spectroscopy was used to study the morphology of silver nanoparticles. The mean size of silver nanoparticles and the components of products were theoretically determined using UV-Vis and X-ray Diffraction spectra. The mole ratio between the silver ion, citric acid and the buffer acid solution (acetic acid) strongly inf
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