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Finally, the influences of the temperature, glycerol initial concentration, and current density on the glycerol electrocatalytic reduction were evaluated. The initial step involved the C-O and C-C bonds cleavage in glycerol plays a crucial role in producing either acetol or ethylene glycol intermediate. This was controlled by the temperature, which low to moderate value is needed to maintain a selective acetol-1,2-propanediol route. Additionally, medium glycerol initial concentration reduced the hydrogen formation and indirectly improve
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