https://www.selleckchem.com/pr....oducts/mpp-dihydroch
Herein, we first present a nickel-catalyzed arylation and alkenylation of tert-cyclobutanols with aryl/alkenyl triflates via a C-C bond cleavage. An array of γ-substituted ketones was obtained in moderate-to-good yields, thus featuring earth-abundant nickel catalysis, broad substrate scope, and simple reaction conditions. Preliminary mechanistic experiments indicated that β-carbon elimination pathways might be involved in the catalytic cycle.A dual platform for forging sp2-sp3 and sp3-sp3 carbon bonds via catalytic β-scissio
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