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The concurrent role played by conformational degrees of freedom and the matrix polarizability in governing TADF is addressed.In the formation of noncovalent complexes, the stacking arrangements of corannulene and fullerene are diverse, most of which are combinations of multiple corannulenes and fullerene. Here, a composition ratio of 2 1 was selected for the complex between corannulene and fullerene (C60 and C7 to investigate the effects of different superposition modes, including concave-convex and convex-convex interactions, on the
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