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The methodology used a set of optimal on-line SFE-SFC-MS/MS extraction parameters for 18 analytes of variable physicochemical properties in three different silica gel-based sample matrices are presented.Current theoretical, two compartment description of integrative passive sampling is renewed to establish a three-compartment model. The developed theoretical description includes external chemical conditions near the receiving phase, conditions inside the receiving phase and the chemically bonded compartments. New variable p, which cont
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