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The coordination chemistry of bidentate aminopyridinato ligands (ApH), in particular 2-aminopyridines, is a highly popular area of research. Due to easy accessibility and versatility, 2-aminopyridines have played a prominent role as alternatives to cyclopentadienyl ligands in coordination chemistry. Easily modifiable steric bulks and the ability for fine-tuning of electronic effects have allowed researchers to control not only the metal-to-ligand stoichiometry but also the properties of their metal complexes. Previously, ligand redistri
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