https://www.selleckchem.com/pr....oducts/cid44216842.h
A dichlorido-bridged dinuclear dysprosium(III) single-molecule magnet [Dy 2 L 2 ( µ -Cl) 2 (THF) 2 ] has been made using a diamine-bis(phenolate) ligand, H 2 L. Magnetic studies show an energy barrier for magnetization reversal ( U eff ) around 1000 K. Exchange-biasing effect is clearly seen in magnetic hysteresis with steps up to 3 K. Ab initio calculations exclude the possibility of pure dipolar origin of this effect leading to the conclusion that super-exchange via the chloride bridging ligands is important. © 2020 WILEY-VCH Verl
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