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In the same flask, a chiral Brønsted acid is added next to engage the isomerization services and products into a stereocontrolled allylboration effect. Architectural variants have been performed on both the allylic alcohols in addition to homoallylboronates. This mild process affords an array of stereochemically congested and complex chiral secondary homoallylic alcohols in large yield, exemplary diastereoselectivity, and often high enantioselectivity.Removal of trace chlorobutane (C isom
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