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Materials with layered crystal structures and large in-plane anisotropy, such black colored phosphorus, current unique properties and thus pledge for applications in digital and photonic devices. Recently, the layered structures of GeS2 and GeSe2 had been utilized for superior polarization-sensitive photodetection into the quick wavelength area because of the large in-plane optical anisotropy and large musical organization space. The very complex, low-symmetr